The physics
The star HD 195521 is actually two stars orbiting each other. We can't see them separately, but their light is recorded together. As they orbit, one moves towards us while the other moves away, and the Doppler effect shifts the light of each star by a different amount.
In the data, each star shows up as a dip. The position of the dip gives that star's velocity along our line of sight, its radial velocity. Observed on three different nights, the two dips move apart, merge, and separate again on the other side.